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that gold could somehow be distilled from human urine。 (the similarity ofcolor seems to have been a factor in his conclusion。) he assembled fifty buckets of humanurine; which he kept for months in his cellar。 by various recondite processes; he converted theurine first into a noxious paste and then into a translucent waxy substance。 none of it yieldedgold; of course; but a strange and interesting thing did happen。 after a time; the substancebegan to glow。 moreover; when exposed to air; it often spontaneously burst into flame。
the mercial potential for the stuff—which soon became known as phosphorus; fromgreek and latin roots meaning “light bearing”—was not lost on eager businesspeople; but thedifficulties of manufacture made it too costly to exploit。 an ounce of phosphorus retailed forsix guineas—perhaps five hundred dollars in today’s money—or more than gold。
at first; soldiers were called on to provide the raw material; but such an arrangement washardly conducive to industrial…scale production。 in the 1750s a swedish chemist named karl(or carl) scheele devised a way to manufacture phosphorus in bulk without the slop or smellof urine。 it was largely because of this mastery of phosphorus that sweden became; andremains; a leading producer of matches。
scheele was both an extraordinary and extraordinarily luckless fellow。 a poor pharmacistwith little in the way of advanced apparatus; he discovered eight elements—chlorine; fluorine;manganese; barium; molybdenum; tungsten; nitrogen; and oxygen—and got credit for none ofthem。 in every case; his finds were either overlooked or made it into publication aftersomeone else had made the same discovery independently。 he also discovered many usefulpounds; among them ammonia; glycerin; and tannic acid; and was the first to see themercial potential of chlorine as a bleach—all breakthroughs that made other peopleextremely wealthy。
scheele’s one notable shorting was a curious insistence on tasting a little of everythinghe worked with; including such notoriously disagreeable substances as mercury; prussic acid(another of his discoveries); and hydrocyanic acid—a pound so famously poisonous that150 years later erwin schr?dinger chose it as his toxin of choice in a famous thoughtexperiment (see page 146)。 scheele’s rashness eventually caught up with him。 in 1786; agedjust forty…three; he was found dead at his workbench surrounded by an array of toxicchemicals; any one of which could have accounted for the stunned and terminal look on hisface。
were the world just and swedish…speaking; scheele would have enjoyed universal acclaim。
instead credit has tended to lodge with more celebrated chemists; mostly from the english…speaking world。 scheele discovered oxygen in 1772; but for various heartbreakinglyplicated reasons could not get his paper published in a timely manner。 instead credit wentto joseph priestley; who discovered the same element independently; but latterly; in thesummer of 1774。 even more remarkable was scheele’s failure to receive credit for thediscovery of chlorine。 nearly all textbooks still attribute chlorine’s discovery to humphrydavy; who did indeed find it; but thirty…six years after scheele had。
although chemistry had e a long way in the century that separated newton and boylefrom scheele and priestley and henry cavendish; it still had a long way to go。 right up to theclosing years of the eighteenth century (and in priestley’s case a little beyond) scientistseverywhere searched for; and sometimes believed they had actually found; things that justweren’t there: vitiated airs; dephlogisticated marine acids; phloxes; calxes; terraqueousexhalations; and; above all; phlogiston; the substance that was thought to be the active agentin bustion。 somewhere in all this; it was thought; there also resided a mysterious élanvital; the force that brought inanimate objects to life。 no one knew where this ethereal essencelay; but two things seemed probable: that you could enliven it with a jolt of electricity (anotion mary shelley exploited to full effect in her novel frankenstein ) and that it existed insome substances but not others; which is why we ended up with two branches of chemistry:
organic (for those substances that were thought to have it) and inorganic (for those that didnot)。
someone of insight was needed to thrust chemistry into the modern age; and it was thefrench who provided him。 his name was antoine…laurent lavoisier。 born in 1743; lavoisierwas a member of the minor nobility (his father had purchased a title for the family)。 in 1768;he bought a practicing share in a deeply despised institution called the ferme générale (orgeneral farm); which collected taxes and fees on behalf of the government。 althoughlavoisier himself was by all accounts mild and fair…minded; the pany he worked for wasneither。 for one thing; it did not tax the rich but only the poor; and then often arbitrarily。 forlavoisier; the appeal of the institution was that it provided him with the wealth to follow hisprincipal devotion; science。 at his peak; his personal earnings reached 150;000 livres a year—perhaps 20 million in today’s money。
three years after embarking on this lucrative career path; he married the fourteen…year…olddaughter of one of his bosses。 the marriage was a meeting of hearts and minds both。 madamelavoisier had an incisive intellect and soon was working productively alongside her husband。
despite the demands of his job and busy social life; they managed to put in five hours ofscience on most days—two in the early morning and three in the evening—as well as thewhole of sunday; which they called their jour de bonheur (day of happiness)。 somehowlavoisier also found the time to be missioner of gunpowder; supervise the building of awall around paris to deter smugglers; help found the metric system; and coauthor thehandbook méthode de nomenclature chimique ; which became the bible for agreeing on thenames of the elements。
as a leading member of the académie royale des sciences; he was also required to take aninformed and active interest in whatever was topical—hypnotism; prison reform; therespiration of insects; the water supply of paris